F-Prime springs to mind...I'll figure out some more when I have time.
In terms of commercial plugins - Messiah Studio? I'm only just getting into it but it has some really nice features. I would love a copy of Syflex Cloth and RealFlow but just can't justify the expense.
Vertibevel, I've heard is nice but since I tend not to be a hard-surface modeller, then I suppose for me its not so important.
If you can call it a plugin as well - ZBrush? Its something that adds to the workflow, not necessarily a plugin.
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